U CHARACTERIZATION OF RHENIUM(V) COMPLEXES WITH PHENOLS USING MASS SPECTROMETRY WITH SELECTED SOFT IONIZATION TECHNIQUES
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10314763" target="_blank" >RIV/00216208:11310/15:10314763 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/00032719.2015.1038552" target="_blank" >http://dx.doi.org/10.1080/00032719.2015.1038552</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00032719.2015.1038552" target="_blank" >10.1080/00032719.2015.1038552</a>
Alternative languages
Result language
angličtina
Original language name
U CHARACTERIZATION OF RHENIUM(V) COMPLEXES WITH PHENOLS USING MASS SPECTROMETRY WITH SELECTED SOFT IONIZATION TECHNIQUES
Original language description
The synthesis, characterization, and mass spectra of oxorhenium(V) complexes with 1,2-dihydroxybenzene, 1,2,3-trihydroxybenzene, and 2,3-dihydroxynaphtalene are reported. Electrospray ionization, atmospheric pressure photoionization, and laser desorption/ionization mass spectra of the complexes showed abundant negatively charged molecular anions and low fragmentation. Calculated similarity indexes showed significant conformity between the computed and experimental isotopic patterns of selected ions andconfirmed correct assignment of elemental composition to m/z values. Electrospray tandem mass spectrometry provided essential information about fragments from molecular ions of studied complexes, making it possible to distinguish among fragment ions andthe ions arising from compounds present in the reaction mixture. Based on the results, mass spectrometry utilizing soft common ionization techniques is useful for monitoring complex formation reaction kinetics and the stabilities of the c
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Analytical Letters
ISSN
0003-2719
e-ISSN
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Volume of the periodical
48
Issue of the periodical within the volume
15
Country of publishing house
US - UNITED STATES
Number of pages
14
Pages from-to
2329-2342
UT code for WoS article
000359732700001
EID of the result in the Scopus database
2-s2.0-84938349407