Bifunctional (Thio)urea-Phosphine Organocatalysts Derived from d-Glucose and -Amino Acids and Their Application to the Enantioselective Morita-Baylis-Hillman Reaction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10314882" target="_blank" >RIV/00216208:11310/15:10314882 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1055/s-0035-1560931" target="_blank" >http://dx.doi.org/10.1055/s-0035-1560931</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1055/s-0035-1560931" target="_blank" >10.1055/s-0035-1560931</a>
Alternative languages
Result language
angličtina
Original language name
Bifunctional (Thio)urea-Phosphine Organocatalysts Derived from d-Glucose and -Amino Acids and Their Application to the Enantioselective Morita-Baylis-Hillman Reaction
Original language description
Novel (thio)urea-tertiary phosphines were developed for use as bifunctional organocatalysts readily available from naturally occurring molecules: saccharides and amino acids. The efficiency of the organocatalysts was demonstrated in the asymmetric Morita-Baylis-Hillman (MBH) reaction of aromatic aldehydes with acrylates. The MBH products were obtained in good yields (up to 85%) and with high enantioselectivities (up to 87% ee).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synlett
ISSN
0936-5214
e-ISSN
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Volume of the periodical
26
Issue of the periodical within the volume
19
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
2690-2696
UT code for WoS article
000365298100012
EID of the result in the Scopus database
2-s2.0-84947713120