Ir-catalyzed C-H silylations of phenyldeazapurines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10315911" target="_blank" >RIV/00216208:11310/15:10315911 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/15:00453586
Result on the web
<a href="http://dx.doi.org/10.1016/j.tetlet.2015.10.089" target="_blank" >http://dx.doi.org/10.1016/j.tetlet.2015.10.089</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.tetlet.2015.10.089" target="_blank" >10.1016/j.tetlet.2015.10.089</a>
Alternative languages
Result language
angličtina
Original language name
Ir-catalyzed C-H silylations of phenyldeazapurines
Original language description
A study of the Ir-catalyzed C-H silylation of 6-phenyl-7-deazapurines or -9-deazapurines with trialkylsilanes revealed that this reaction preferentially proceeded via ortho-silylation at the aryl group due to the directing effect of the N1 nitrogen of the deazapurine, rather than C-H silylation at the heterocycle which was only a minor side-reaction. A preparative protocol for the ortho-silylation of aryldeazapurines is. presented.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F12%2F0205" target="_blank" >GAP207/12/0205: Development of novel methodologies of C-H activations of purines, deazapurines, pyrimidines and related heterocycles</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Tetrahedron Letters
ISSN
0040-4039
e-ISSN
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Volume of the periodical
56
Issue of the periodical within the volume
49
Country of publishing house
GB - UNITED KINGDOM
Number of pages
3
Pages from-to
6860-6862
UT code for WoS article
000365366500011
EID of the result in the Scopus database
2-s2.0-84947556568