Differential pulse voltammetric determination of 4-nitroaniline using a glassy carbon electrode: comparative study between cathodic and anodic quantification

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F16%3A10318277" target="_blank" >RIV/00216208:11310/16:10318277 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1007/s00706-015-1596-3" target="_blank" >http://dx.doi.org/10.1007/s00706-015-1596-3</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s00706-015-1596-3" target="_blank" >10.1007/s00706-015-1596-3</a>

Result language

angličtina

Original language name

Differential pulse voltammetric determination of 4-nitroaniline using a glassy carbon electrode: comparative study between cathodic and anodic quantification

Original language description

Differential pulse voltammetry with a glassy carbon electrode was used for the determination of trace amounts of 4-nitroaniline in Britton-Robinson buffer at pH 2.0 as an optimal base electrolyte. 4-Nitroaniline can be determined by differential pulse voltammetry directly using either its electrochemical oxidation or reduction. The calibration curve was measured for both reactions in the same concentration range from 2 to 100 mu mol dm(-3). The calculated limits of detection and quantification are 0.2 and 0.7 mu mol dm(-3) (RSD 6.62 % and R (2) = 0.9906 for n = 5) for cathodic reduction and 0.3 and 1.0 mu mol dm(-3) (RSD 7.62 % and R (2) = 0.9995 for n = 5) for anodic oxidation. [GRAPHICS] .

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

<a href="/en/project/GBP206%2F12%2FG151" target="_blank" >GBP206/12/G151: Center of novel approaches to bioanalysis and molecular diagnostics</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2016

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Monatshefte für Chemie

ISSN

0026-9247

e-ISSN

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Volume of the periodical

147

Issue of the periodical within the volume

1

Country of publishing house

AT - AUSTRIA

Number of pages

8

Pages from-to

111-118

UT code for WoS article

000367521400015

EID of the result in the Scopus database

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