COPPER-CATALYZED REACTIONS: RESEARCH IN THE GAS PHASE

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F16%3A10323714" target="_blank" >RIV/00216208:11310/16:10323714 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/mas.21464" target="_blank" >http://dx.doi.org/10.1002/mas.21464</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/mas.21464" target="_blank" >10.1002/mas.21464</a>

Result language
angličtina
Original language name
COPPER-CATALYZED REACTIONS: RESEARCH IN THE GAS PHASE
Original language description
Electrospray ionization mass spectrometry (ESI-MS) is becoming an important tool for mechanistic studies in organic and organometallic chemistry. It allows investigation of reaction mixtures including monitoring of reactants, products, and intermediates, studying properties of the intermediates and their reactivity. Studying the reactive species in the gas phase can be advantageously combined with theoretical calculations. This review is focused on ESI-MS studies of copper-catalyzed reactions. Possible effects of the electrospray process on the transfer of the copper complexes to the gas phase are discussed. The plethora of mass spectrometric approaches is demonstrated on copper mediated C-H activations, cross coupling reactions, rearrangements, organocuprate chemistry, and other examples. (c) 2015 Wiley Periodicals, Inc.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA14-20077S" target="_blank" >GA14-20077S: Non-heme iron catalysts: Investigation of reaction mechanisms</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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