The structure of a propagating MgAl2O4/MgO interface: linked atomic- and μ-scale mechanisms of interface motion

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F16%3A10327827" target="_blank" >RIV/00216208:11310/16:10327827 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1080/14786435.2016.1205233" target="_blank" >http://dx.doi.org/10.1080/14786435.2016.1205233</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/14786435.2016.1205233" target="_blank" >10.1080/14786435.2016.1205233</a>

Result language

angličtina

Original language name

The structure of a propagating MgAl2O4/MgO interface: linked atomic- and μ-scale mechanisms of interface motion

Original language description

To understand how a new phase forms between two reactant layers, MgAl2O4 (spinel) has been grown between MgO (periclase) and Al2O3 (corundum) single crystals under defined temperature and load. Electron backscatter diffraction data show a topotaxial relationship between the MgO reactant and the MgAl2O4 reaction product. These MgAl2O4 grains are misoriented from perfect alignment with the MgO substrate by similar to 2-4 degrees, with misorientation axes concentrated in the interface plane. Further study using atomic resolution scanning transmission electron microscopy shows that in 2D the MgAl2O4/MgO interface has a periodic configuration consisting of curved segments (convex towards MgO) joined by regularly spaced misfit dislocations occurring every similar to 4.5nm (similar to 23 atomic planes). This configuration is observed along the two equivalent [100] directions parallel to the MgAl2O4/MgO interface, indicating that the 3D geometry of the interface is a grid of convex protrusions of MgAl2O4 into MgO. At each minimum between the protrusions is a misfit dislocation. This geometry results from the coupling between long-range diffusion, which supplies Al3+ to and removes Mg2+ from the reaction interface, and interface reaction, in which climb of the misfit dislocations is the rate-limiting process. The extra oxygen atoms required for dislocation climb were likely derived from the reactant MgO, leaving behind oxygen vacancies that eventually form pores at the interface. The pores are dragged along by the propagating reaction interface, providing additional resistance to interface motion. The pinning effect of the pores leads to doming of the interface on the scale of individual grains.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

DB - Geology and mineralogy

OECD FORD branch

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Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2016

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Philosophical Magazine

ISSN

1478-6435

e-ISSN

—

Volume of the periodical

96

Issue of the periodical within the volume

23

Country of publishing house

GB - UNITED KINGDOM

Number of pages

16

Pages from-to

2488-2503

UT code for WoS article

000381288000006

EID of the result in the Scopus database

2-s2.0-84978523923