Determination of rhenium complexes with 1,2-dihydroxybenzene and 1,2,3-trihydroxy-benzene by CZE compared with HPLC-UV/MS
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F16%3A10336683" target="_blank" >RIV/00216208:11310/16:10336683 - isvavai.cz</a>
Result on the web
<a href="http://web.natur.cuni.cz/analchem/isc/isc12.pdf" target="_blank" >http://web.natur.cuni.cz/analchem/isc/isc12.pdf</a>
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Determination of rhenium complexes with 1,2-dihydroxybenzene and 1,2,3-trihydroxy-benzene by CZE compared with HPLC-UV/MS
Original language description
Two analytical methods, HPLC and CZE, have been successfully used for determination and separation of reaction mixtures containing rhenium complexes, a potentially important group in medicine, prepared by a reaction of tetrabutylammonium tetrachlorooxo-rhenate as rhenium precursor and complex forming ligands 1,2,3-trihydroxybenzene and 1,2-dihydroxybenzene. Borate buffers in the range of pH6.0-11.5were tested as background electrolytes, all of them provide complete resolution of all components of a reaction mixtures within 10 min. Effective electrophoretic mobilities of separated components were calculated and relevant graphs were designed. Optimal conditions for HPLC-UV/MS separation of reaction mixture components have been successfully discovered for the Agilent Zorbax SAX column, fully resolved peaks were identified by amassspectrometry with electrospray ionization.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
PROCEEDINGS OF THE 12TH INTERNATIONAL STUDENTS CONFERENCE MODERN ANALYTICAL CHEMISTRY
ISBN
978-80-7444-044-1
ISSN
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e-ISSN
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Number of pages
7
Pages from-to
73-79
Publisher name
CHARLES UNIV, FAC SCIENCE
Place of publication
PRAGUE 2
Event location
Prague
Event date
Sep 22, 2016
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
000391253800014