Synthesis and structural characterization of a ferrocene ether-diphosphine and its Cu(I) complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F17%3A10362327" target="_blank" >RIV/00216208:11310/17:10362327 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.jorganchem.2017.06.012" target="_blank" >https://doi.org/10.1016/j.jorganchem.2017.06.012</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2017.06.012" target="_blank" >10.1016/j.jorganchem.2017.06.012</a>

Result language
angličtina
Original language name
Synthesis and structural characterization of a ferrocene ether-diphosphine and its Cu(I) complexes
Original language description
Bis{[1'-(diphenylphosphino) ferrocenyl] methyl} ether (3) was prepared in two steps from the [1'-(diphenylphosphino) ferrocenyl]methanol-borane (1:1) adduct and structurally characterized. Compound 3 reacted with copper(I) halides to afford structurally similar, cyclic binuclear complexes of the type [CuX{m(P, P')-3}]2 (X = Cl, Br and I) featuring equivalent Cu(I) centers with trigonal P2X donor sets symmetrically bridged by the diphosphine ligand.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA15-11571S" target="_blank" >GA15-11571S: Unsymmetric phosphinoferrocene donors</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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