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Alterations of thorium oxalate morphology by changing elementary precipitation conditions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F17%3A10364229" target="_blank" >RIV/00216208:11310/17:10364229 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1016/j.jnucmat.2017.06.027" target="_blank" >https://doi.org/10.1016/j.jnucmat.2017.06.027</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jnucmat.2017.06.027" target="_blank" >10.1016/j.jnucmat.2017.06.027</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Alterations of thorium oxalate morphology by changing elementary precipitation conditions

  • Original language description

    Oxalates of actinide elements are widely used in research and industry mainly due to their low solubility in aqueous solution and easy conversion to oxide. Although thorium oxide is worldwide mostly produced by the oxalate precipitation and conversion route, the powder morphology obtained through this process is known to inhibit the packing and sintering step of the pellet production. The presented work investigates the effects of oxalate precipitation conditions on the final powder morphology. Among the precipitation conditions considered are: pH of the thorium feed solution, concentration, temperature and the order of addition (thorium solution in oxalic acid solution and vice versa) known as reverse/direct strike. Herein, we show that the morphology of the final oxalate depends significantly on the above mentioned precipitation parameters.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Nuclear Materials

  • ISSN

    0022-3115

  • e-ISSN

  • Volume of the periodical

    493

  • Issue of the periodical within the volume

    September

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    255-263

  • UT code for WoS article

    000408044000028

  • EID of the result in the Scopus database

    2-s2.0-85021414226