Synthesis and structural characterization of ferrocene phosphines modified with polar pendants and their palladium(II) complexes. Part II: N-aminocarbonyl and N-acyl phosphinoferrocene carbohydrazides

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10374459" target="_blank" >RIV/00216208:11310/18:10374459 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.jorganchem.2018.02.044" target="_blank" >https://doi.org/10.1016/j.jorganchem.2018.02.044</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2018.02.044" target="_blank" >10.1016/j.jorganchem.2018.02.044</a>

Result language
angličtina
Original language name
Synthesis and structural characterization of ferrocene phosphines modified with polar pendants and their palladium(II) complexes. Part II: N-aminocarbonyl and N-acyl phosphinoferrocene carbohydrazides
Original language description
The reactions of 1'-(diphenylphosphino)-1-(hydrazinylcarbonyl)ferrocene, Ph(2)PfcCONHNH(2) (1; fc = ferrocene-1,1'-diyl), with HNCO, EtNCO, PhNCO, Me2NC(O)Cl/pyridine, and Ac2O/NEt3 produced the corresponding N-functionalized derivatives Ph(2)PfcCONHNHC(O)Y (1a-e), where Y = NH2 (a), NHEt (b), NHPh (c), NMe2 (d), and Me (e). Compounds 1a-e were used as ligands (L) to prepare Pd(II) bis(phosphine) complexes [PdCl2(L-kappa P)(2)] (3a-e) and two series of Pd(II) complexes bearing an auxiliary 2-[(dimethylamino-kappa N)methyl]phenyl-kappa C-1 (L-NC) ligand, namely, [(L-NC)PdCl(L-kappa P)] (4a-e) and [(L-NC)Pd(L-kappa O-2,P)][SbF6] (5a-e). The crystal structures of compounds 1a, 1c, 1e, the phosphine oxide of 1e (i.e., compound 2e), and complexes 3c . 4CH(2)Cl(2) . 2CH(3)OH, 3e . 4CH(3)OH, 4e, and 5e . (2.5)CHCl(3) were determined by single-crystal X-ray diffraction analysis. Hydrogen bonding interactions observed in the solid-state structures of these compounds are discussed.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA13-08890S" target="_blank" >GA13-08890S: Polar ferrocene amidophosphine ligands for catalytic applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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