Near- and Mid-IR Gas-Phase Absorption Spectra of H-2@C-60(+)-He

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10383309" target="_blank" >RIV/00216208:11310/18:10383309 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.jpca.8b06222" target="_blank" >https://doi.org/10.1021/acs.jpca.8b06222</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpca.8b06222" target="_blank" >10.1021/acs.jpca.8b06222</a>

Result language
angličtina
Original language name
Near- and Mid-IR Gas-Phase Absorption Spectra of H-2@C-60(+)-He
Original language description
Near- and mid-IR absorption spectra of endohedral H-2@C-60(+) have been measured using He-tagging. The samples have been prepared using a "molecular surgery" synthetic approach and were ionized and spectroscopically characterized in the gas phase. In contrast to neutral C-60 and H-2@C-60, the corresponding He-tagged cationic species show distinct spectral differences. Shifts and line splittings in the near- and mid-IR regions indicate the influence of the caged hydrogen molecule on both the electronic ground and excited states. Possible relevance to astronomy is discussed.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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