Ruthenium(II) Bipyridyl Complexes with C^C* Cyclometalated Mesoionic Carbene Ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10385345" target="_blank" >RIV/00216208:11310/18:10385345 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.organomet.8b00637" target="_blank" >https://doi.org/10.1021/acs.organomet.8b00637</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.organomet.8b00637" target="_blank" >10.1021/acs.organomet.8b00637</a>
Alternative languages
Result language
angličtina
Original language name
Ruthenium(II) Bipyridyl Complexes with C^C* Cyclometalated Mesoionic Carbene Ligands
Original language description
The synthesis of four 2,2'-bipyridyl ruthenium(II) complexes with cyclometalating mesoionic 1,2,3-triazolylidene ligands via their respective p-cymene ruthenium(II) precursors is presented. Solid-state structures confirm the formation of the proposed complexes, which were characterized by UV/vis and electrochemical experiments as well as time-dependent DFT calculations including NTO analysis. The title motif shows improved photophysical properties compared to structurally related ruthenium(II) complexes with C^C* cyclometalating imidazole-based N-heterocyclic carbene ligands. Due to their electronic properties, the presented dyes are promising candidates for an application in dye-sensitized solar cells.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
37
Issue of the periodical within the volume
24
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
4619-4629
UT code for WoS article
000454567200012
EID of the result in the Scopus database
2-s2.0-85056827408