Monitoring the assembly-disassembly-organisation-reassembly process of germanosilicate UTL through in situ pair distribution function analysis
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10386133" target="_blank" >RIV/00216208:11310/18:10386133 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1039/c8ta04320e" target="_blank" >https://doi.org/10.1039/c8ta04320e</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8ta04320e" target="_blank" >10.1039/c8ta04320e</a>
Alternative languages
Result language
angličtina
Original language name
Monitoring the assembly-disassembly-organisation-reassembly process of germanosilicate UTL through in situ pair distribution function analysis
Original language description
A study into the disassembly and organisation steps of the ADOR process has been undertaken through in situ Pair Distribution Function (PDF) analysis. Three aqueous systems (water, 6 M HCl and 12 M HCl) were introduced to a parent zeolite germanosilicate UTL in a cell. Hydrolysis could be clearly seen when UTL was exposed to water over a period of 8 h, forming the disorder layered material, IPC-1P. In hydrochloric acid, the hydrolysis step is too quick to observe and a Ge-Cl containing species could be seen. In 6 M HCl, the rearrangement of the interlayer region began after an induction period of 8 h, with the process still occurring after 15 h. In 12 M HCl, the rearrangement appears to have come to an end after only 6 h.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Materials Chemistry A
ISSN
2050-7488
e-ISSN
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Volume of the periodical
6
Issue of the periodical within the volume
35
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
17011-17018
UT code for WoS article
000445218000030
EID of the result in the Scopus database
2-s2.0-85053511914