A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F19%3A10404973" target="_blank" >RIV/00216208:11310/19:10404973 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=eK_5tlrDVl" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=eK_5tlrDVl</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9ce00098d" target="_blank" >10.1039/c9ce00098d</a>

Result language
angličtina
Original language name
A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release
Original language description
Single crystal CPO-27-Mg, -Zn and its structural isomer UTSA-74 have been prepared through use of acid modulators; salicylic acid and benzoic acid, respectively. Salicylic acid directed the synthesis of CPO-27-Mg/Zn whereas benzoic acid the synthesis of UTSA-74. Through in-house SCXRD, DMF was seen to bind to the Zn2+ and water to the Mg2+ metal sites in CPO-27-M. Although the synthesis conditions were analogous for UTSA-74, DMF is too large to bind due to the proximity of the binding sites. A dissolution-recrystallisation transformation was examined from UTSA-74 to CPO-27-Zn. The release of nitric oxide was measured for each material.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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