Investigation of subglacial weathering under the Greenland Ice Sheet using silicon isotopes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F19%3A10407804" target="_blank" >RIV/00216208:11310/19:10407804 - isvavai.cz</a>

Result on the web

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=-Zu5lhbH35" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=-Zu5lhbH35</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.gca.2018.12.033" target="_blank" >10.1016/j.gca.2018.12.033</a>

Result language

angličtina

Original language name

Investigation of subglacial weathering under the Greenland Ice Sheet using silicon isotopes

Original language description

Subglacial chemical weathering plays a key role in global silicate weathering budgets, contributing to the cycling of silicon (Si) in terrestrial and marine systems and the potential drawdown of carbon dioxide from the atmosphere. Here, we use data from two Greenland Ice Sheet (GrIS) catchments to demonstrate how Si isotopes from dissolved and amorphous particulate fractions (delta30DSi and delta30 ASi respectively) can be used together with major ion data to assess the degree of secondary silicate weathering product formation and redissolution in subglacial environments. We compare a time-series of summer melt seasons from the two study sites, which differ in catchment size (similar to 600 km2 for Leverett Glacier (LG) and similar to 36 km2 for Kiattuut Sermiat (KS)). Subglacial waters from LG have elevated Na+ and K+ ions in relation to Ca (2+) and Mg2+ ions, indicating a predominance of silicate weathering, whilst meltwaters from KS are characterised by carbonate weathering (hydrolysis and carbonation) throughout the melt season. Both catchments have mean delta30DSi values substantially lower than average riverine values (KS 0.41 parts per thousand, LG -0.25 parts per thousand, versus a global riverine mean of 1.25 parts per thousand) and display a seasonal decline, which is more pronounced at LG. The delta30 ASi values (discharge weighted mean values KS -0.44 per mille parts per thousand, LG -0.22 per mille parts per thousand) are lighter than the bedrock (mean values KS -0.18 +/- 0.12 per mille parts per thousand, LG 0.00 +/- 0.07 per mille parts per thousand) in both catchments, indicating a secondary weathering product origin or leaching of lighter isotopes during initial weathering of crushed rock. When used in combination, the major ion and silicon isotope data reveal that the extent of silicate weathering and secondary phase redissolution are more pronounced at LG compared to KS. Contrasting weathering regimes and subglacial hydrology between catchments need to be considered when estimating the delta Si-30 composition of silica exported into polar oceans from the GrIS, with larger catchments likely to produce fluxes of lighter delta Si-30. As larger catchments dominate freshwater export to the ocean, GrIS meltwater is likely to be very light in isotopic composition, and the flux is likely to increase with ice melt as the climate warms.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10511 - Environmental sciences (social aspects to be 5.7)

Project

<a href="/en/project/GJ15-17346Y" target="_blank" >GJ15-17346Y: The bright future of subglacial ecosystems: Impacts of deglaciation on microbial activity and carbon cycling at glacier beds</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Geochimica et Cosmochimica Acta

ISSN

0016-7037

e-ISSN

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Volume of the periodical

247

Issue of the periodical within the volume

January

Country of publishing house

US - UNITED STATES

Number of pages

16

Pages from-to

191-206

UT code for WoS article

000456159500012

EID of the result in the Scopus database

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