Trapping ionic dimers of dinuclear peroxido mandelato complexes of vanadium(V) into cavities constructed from Δ- and Λ-[Ni(phenanthroline)3](2+) cations: a precursor to Ni(VO3)2
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F19%3A10465983" target="_blank" >RIV/00216208:11310/19:10465983 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=YJUXglpRG2" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=YJUXglpRG2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11243-019-00344-0" target="_blank" >10.1007/s11243-019-00344-0</a>
Alternative languages
Result language
angličtina
Original language name
Trapping ionic dimers of dinuclear peroxido mandelato complexes of vanadium(V) into cavities constructed from Δ- and Λ-[Ni(phenanthroline)3](2+) cations: a precursor to Ni(VO3)2
Original language description
A nickel-vanadium metal-organic hybrid compound [Ni(phen)(3)](2)[(V2O2(O-2)(2)((S)-mand)(2))][(V2O2(O-2)(2)((R)-mand)(2))] . 18H2O (phen = 1,10-phenanthroline, mand(2-) = mandelato(2-) ligand, C6H5-CO-COO2-) (1) was prepared and characterized by spectral methods, X-ray structure analysis and simultaneous DTA and TG measurements. The crystal structure of 1 contains both Delta and Lambda enantiomers of the [Ni(phen)(3)](2+) cations that construct sandwich layers along the crystallographic axis c, in between which sit the vanadium(V) complex anions. These are present as ionic dimers in the form of a robust {[(V2O2(O-2)(2)((S)-mand)(2))][(V2O2(O-2)(2)((R)-mand)(2))]}(4-) species. The two individual anions are coupled by a pair of weak, yet significant attractions between two vanadium atoms and two peroxido ligands of the adjacent anion at V-O distances 2.660 angstrom. The (51)V NMR spectrum of the compound in DMSO solution revealed a complicated course of decomposition reactions of the anion, which led to formation of the [(V2O4(S,R-mand)(2)](2-) anion as a single product. The metal-organic hybrid compound 1 is converted by thermal decomposition into a potential anode material for lithium-ion batteries Ni(VO3)(2).
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/EF15_003%2F0000417" target="_blank" >EF15_003/0000417: Center for Advanced Materials: Design, Synthesis, and Applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Transition Metal Chemistry
ISSN
0340-4285
e-ISSN
1572-901X
Volume of the periodical
44
Issue of the periodical within the volume
8
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
8
Pages from-to
747-754
UT code for WoS article
000505178500007
EID of the result in the Scopus database
2-s2.0-85069495366