Applications of Bolm's Ligand in Enantioselective Synthesis

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10414565" target="_blank" >RIV/00216208:11310/20:10414565 - isvavai.cz</a>

Result on the web

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=Bi.p-3y2E-" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=Bi.p-3y2E-</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/molecules25040958" target="_blank" >10.3390/molecules25040958</a>

Result language

angličtina

Original language name

Applications of Bolm's Ligand in Enantioselective Synthesis

Original language description

One pathway for the preparation of enantiomerically pure compounds from prochiral substrates is the use of metal complex catalysis with chiral ligands. Compared to the other frequently used chiral ligands, chiral 2,2&apos;-bipyridines have been underexploited, despite the data indicating that such ligands have considerable potential in synthetic chemistry. One of those is the so-called Bolm&apos;s ligand, a compound possessing chiral alcohol moieties in the side chains attached to the 2,2&apos;-bipyridine scaffold. Various metal salts have been used in combination with Bolm&apos;s ligand as potent catalysts able to bring about enantioselective alkylations, allylations, conjugate additions, desymmetrization of meso-epoxides, aldol reactions, etc. This review aims to summarize Bolm&apos;s ligand applications in the area of enantioselective synthesis over the last three decades since its preparation.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10401 - Organic chemistry

Project

<a href="/en/project/GA17-07707S" target="_blank" >GA17-07707S: Development of New Syntheses of Azaheterocycles</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2020

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Molecules

ISSN

1420-3049

e-ISSN

—

Volume of the periodical

25

Issue of the periodical within the volume

4

Country of publishing house

CH - SWITZERLAND

Number of pages

14

Pages from-to

958

UT code for WoS article

000522454500194

EID of the result in the Scopus database

2-s2.0-85079837819