Dimeric Oxidovanadium(IV) Complex Bearing 1,10-Phenanthroline
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10418706" target="_blank" >RIV/00216208:11310/20:10418706 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/20:39916508
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=GlZro_hxVc" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=GlZro_hxVc</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1134/S1063774520070056" target="_blank" >10.1134/S1063774520070056</a>
Alternative languages
Result language
angličtina
Original language name
Dimeric Oxidovanadium(IV) Complex Bearing 1,10-Phenanthroline
Original language description
New crystals of di-mu-methoxido-bis[(2-ethylhexanoato-kappa O)oxido(1,10-phenanthroline-kappa N-2,N')vanadium(IV)], C42H52N4O8V2, have been synthesized, characterized by elemental analysis, infrared spectroscopy, electron paramagnetic resonance and X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P2(1)/c: a = 13.0656(11) angstrom, b = 9.1474(8) angstrom, c = 17.0299(14) angstrom, beta = 94.387(4)degrees, Z = 2, R-gt = 0.0617, wR(F-2) = 0.169, T = 150(2) K. The dimeric oxidovanadium(IV) complex consists of two [(VO)-O-IV(OCOC7H15)(phen)] units connected with two methanolate bridges. The vanadium atoms have a distorted octahedral environment with four oxygen and two nitrogen atoms. The V=O bond length is 1.601(3) angstrom; the V-O bond lengths in the symmetrical V2O2 core are 1.973(2) and 2.007(3) angstrom. The vanadium-oxygen bond lengths in the carboxylate are 1.974(3) angstrom. The V-N interatomic distances depend on the configuration towards the oxidoligand. Preliminary experiments on solvent-borne alkyd resins revealed promising catalytic activity in the auto-oxidation process.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Crystallography Reports
ISSN
1063-7745
e-ISSN
—
Volume of the periodical
65
Issue of the periodical within the volume
7
Country of publishing house
RU - RUSSIAN FEDERATION
Number of pages
4
Pages from-to
1129-1132
UT code for WoS article
000592546300007
EID of the result in the Scopus database
2-s2.0-85096580623