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Dimeric Oxidovanadium(IV) Complex Bearing 1,10-Phenanthroline

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10418706" target="_blank" >RIV/00216208:11310/20:10418706 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216275:25310/20:39916508

  • Result on the web

    <a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=GlZro_hxVc" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=GlZro_hxVc</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1134/S1063774520070056" target="_blank" >10.1134/S1063774520070056</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Dimeric Oxidovanadium(IV) Complex Bearing 1,10-Phenanthroline

  • Original language description

    New crystals of di-mu-methoxido-bis[(2-ethylhexanoato-kappa O)oxido(1,10-phenanthroline-kappa N-2,N&apos;)vanadium(IV)], C42H52N4O8V2, have been synthesized, characterized by elemental analysis, infrared spectroscopy, electron paramagnetic resonance and X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P2(1)/c: a = 13.0656(11) angstrom, b = 9.1474(8) angstrom, c = 17.0299(14) angstrom, beta = 94.387(4)degrees, Z = 2, R-gt = 0.0617, wR(F-2) = 0.169, T = 150(2) K. The dimeric oxidovanadium(IV) complex consists of two [(VO)-O-IV(OCOC7H15)(phen)] units connected with two methanolate bridges. The vanadium atoms have a distorted octahedral environment with four oxygen and two nitrogen atoms. The V=O bond length is 1.601(3) angstrom; the V-O bond lengths in the symmetrical V2O2 core are 1.973(2) and 2.007(3) angstrom. The vanadium-oxygen bond lengths in the carboxylate are 1.974(3) angstrom. The V-N interatomic distances depend on the configuration towards the oxidoligand. Preliminary experiments on solvent-borne alkyd resins revealed promising catalytic activity in the auto-oxidation process.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Crystallography Reports

  • ISSN

    1063-7745

  • e-ISSN

  • Volume of the periodical

    65

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    RU - RUSSIAN FEDERATION

  • Number of pages

    4

  • Pages from-to

    1129-1132

  • UT code for WoS article

    000592546300007

  • EID of the result in the Scopus database

    2-s2.0-85096580623