A composite of imprinted polypyrrole beads and reduced graphene oxide for specific electrochemical sensing of atrazine in complex matrices

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10419913" target="_blank" >RIV/00216208:11310/20:10419913 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=XB83HT70Cr" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=XB83HT70Cr</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s00706-020-02593-7" target="_blank" >10.1007/s00706-020-02593-7</a>

Result language
angličtina
Original language name
A composite of imprinted polypyrrole beads and reduced graphene oxide for specific electrochemical sensing of atrazine in complex matrices
Original language description
Atrazine-imprinted reduced graphene oxide composite with its enhanced functionalities and porous surface was successfully synthesized and applied for the selective determination of atrazine in complex matrices. Scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction studies revealed the imprinted polypyrrole beads formation on the reduced graphene oxide lining. Resultant composite was used to modify screen-printed electrode which then showed improved properties for voltammetric determination of atrazine. Measurements were carried out via square wave voltammetry giving a peak at - 0.9 V corresponding to the reduction of atrazine heterocyclic moiety. Obtained LOD and LOQ for atrazine were found to be 0.4 nmol/dm(3) and 1.2 nmol/dm(3), respectively, at optimized parameters. The method was applied for the atrazine determination in complex aqueous matrices.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry

Project
<a href="/en/project/GA20-01589S" target="_blank" >GA20-01589S: New strategies for improving sensing properties of novel electrode materials via their surface pretreatment or modification</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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