Intermolecular interactions in the crystal structures of chlorogold(I) complexes with N-phosphinoamide ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F21%3A10427843" target="_blank" >RIV/00216208:11310/21:10427843 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=hfeLLD9QrI" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=hfeLLD9QrI</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2020.120138" target="_blank" >10.1016/j.ica.2020.120138</a>

Result language
angličtina
Original language name
Intermolecular interactions in the crystal structures of chlorogold(I) complexes with N-phosphinoamide ligands
Original language description
[AuCl{RC(O)NHPPh2-κP}]gold(I) complexes with varying amide substituents (R = Me, Ph and ferrocenyl) were prepared, characterized by elemental analysis and spectroscopic methods (mass spectrometry and multinuclear NMR and IR spectroscopy) and further studied by single-crystal X-ray crystallography with a particular focus on solid-state interactions. In all cases, the crystal assembly was based mainly on conventional hydrogen bonds between the amide moieties. However, while in chloroform-solvated [AuCl{MeC(O)NHPPh2-κP}], these interactions were supported by pi center dot center dot center dot pi stacking of aromatic rings, in the crystal structures of the complexes bearing phenyl and ferrocenyl substituents, they cooperated with aurophilic interactions of the Au(I) centers, which in turn affected the C = O center dot center dot center dot HN hydrogen bonds.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA19-09334S" target="_blank" >GA19-09334S: Uncoventional ferrocene phosphines</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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