Synthesis and coordination of a hybrid phosphinoferrocene sulfonamide ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F21%3A10427845" target="_blank" >RIV/00216208:11310/21:10427845 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=SUG9LIBtW2" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=SUG9LIBtW2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1nj00080b" target="_blank" >10.1039/d1nj00080b</a>

Result language
angličtina
Original language name
Synthesis and coordination of a hybrid phosphinoferrocene sulfonamide ligand
Original language description
In order to expand the family of hybrid phosphinoferrocene ligands, a novel phosphinoferrocene sulfonamide ligand, Ph(2)PfcNHSO(2)Me (1, fc = ferrocene-1,1'-diyl), was synthesised through a reaction between P-protected phosphinoamine Ph(2)PfcNH(2) . BH3 and MeSO2Cl followed by deprotection of the Ph(2)PfcNHSO(2)Me . BH3 (2) intermediate. Compound 1 coordinates as a functional phosphine ligand, producing Pd(II) complexes [PdCl(μ-Cl)(1-κP)](2) (4) or [PdCl2(1-κP)(2)] (5) from [PdCl2(cod)] (cod = cycloocta-1,5-diene) depending on the stoichiometry. The reaction of 1 with [(L-NC)Pd(μ-Cl)](2) also produces a phosphine complex, [(L-NC)PdCl(1-κP)] (6; L-NC = 2-[(dimethylamino-N)methyl]phenyl-κC-1), which was converted into the neutral bis-chelate complex [(L-NC)Pd(Ph(2)PfcNSO(2)Me-κP-2,N)] (7) upon treatment with potassium tert-butoxide; the corresponding cationic chelate [(L-NC)Pd(Ph(2)PfcNHSO(2)Me-κP-2,O)](+) could not be isolated. All compounds were characterised by elemental analysis and spectroscopic methods (NMR, IR and MS). In addition, the crystal structure of 1, 2, and 4-7 were determined (for solvated compounds in some cases), and the electrochemical properties of 1, 2, 6 and 7 were studied by cyclic voltammetry.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA19-09334S" target="_blank" >GA19-09334S: Uncoventional ferrocene phosphines</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)