Synthesis, Coordination and Electrochemistry of a Ferrocenyl-Tagged Aminobisphosphane Ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F21%3A10434120" target="_blank" >RIV/00216208:11310/21:10434120 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=gxBBcQTejx" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=gxBBcQTejx</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.202100558" target="_blank" >10.1002/ejic.202100558</a>

Result language
angličtina
Original language name
Synthesis, Coordination and Electrochemistry of a Ferrocenyl-Tagged Aminobisphosphane Ligand
Original language description
Introducing a ferrocene moiety into a molecule results in the incorporation of a metal center and a redox active moiety. This contribution describes the synthesis of FcN(CH2PPh2)(2) (1; Fc=ferrocenyl), a ferrocene analog of the widely studied bis-phosphane pincer ligands, RN(CH2PPh2)(2). Compound 1 was studied as a ligand in complexes of Group 10 and 11 metal ions. The following compounds were synthesized and characterized using a combination of spectroscopic methods and single-crystal X-ray diffraction analysis: the square planar complexes [MX2(1-κ(2)P,P')] (M/X=Ni/Cl, Pd/Cl, Pd/Br, Pd/I and Pt/Cl) and the tetrahedral complexes [M(1-.kappa-(2)P,P')(2)]X (M/X=Cu/PF6, Ag/SbF6 and Au/SbF6). Furthermore, a pair of open and cyclic digold(I) complexes containing bis-phosphane 1 as a P,P-bridging ligand, viz. [(μ(P,P')-1)(AuCl)(2)] and [(mu(P,P')-1)(2)Au-2][SbF6](2), were isolated. Ligand 1, the corresponding phosphane selenide 1-Se and all complexes (except for the poorly soluble [(mu(P,P')-1)(2)Au-2][SbF6] and unstable [Ag(1-κ(2)P,P')(2)][SbF6]) were further analyzed by cyclic voltammetry.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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