Controllable Zeolite AST Crystallization: Between Classical and Reversed Crystal Growth
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F22%3A10453440" target="_blank" >RIV/00216208:11310/22:10453440 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=NXUKQi0.d2" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=NXUKQi0.d2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202200590" target="_blank" >10.1002/chem.202200590</a>
Alternative languages
Result language
angličtina
Original language name
Controllable Zeolite AST Crystallization: Between Classical and Reversed Crystal Growth
Original language description
Crystal growth mechanisms govern a wide range of properties of crystalline materials. Reversed crystal growth is one of the nonclassical mechanisms observed in many materials. However, the reversed crystallization starting from amorphous aggregates and the key factors driving this growth remain elusive. Here, we describe a characteristic model of reversed crystal growth representing the inner structure and crystallinity development of aggregates studied by microscopy and nano X-ray computed tomography. By adjusting the synthesis conditions, the fundamental function of the structure-directing agent, which determines the crystallization pathway, was revealed. As a result, the crystal growth mode can be "switched" from the classical route at a low ratio of SDA/framework elements to reversed growth at a high ratio. Our findings provide further insights into crystal growth control, which is crucial for improving synthesis protocols and designing various forms of crystalline materials.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
1521-3765
Volume of the periodical
28
Issue of the periodical within the volume
35
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
e202200590
UT code for WoS article
000789874600001
EID of the result in the Scopus database
2-s2.0-85129254987