Two New Polar Antimony(III) Tartrates with Unusual Structural Building Units

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F23%3A10474724" target="_blank" >RIV/00216208:11310/23:10474724 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11320/23:10474724
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=yYxirrGEtg" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=yYxirrGEtg</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/crat.202300194" target="_blank" >10.1002/crat.202300194</a>

Result language
angličtina
Original language name
Two New Polar Antimony(III) Tartrates with Unusual Structural Building Units
Original language description
Large single crystals of polar tetragonal thallium antimony(III) tartrate dihydrate, Tl(2)[Sb2((+)C4H2O6)2].2H2O, are grown. The crystal structure (s.g. P41), which contains the binuclear complex group [Sb2(C4H2O6)2](2-) and dimer groups [Tl2O8(H2O)2], is given, together with vibrational spectra, refractive indices and their dispersion, and an analysis of SHG phase matching possibility and SHG powder measurements. The crystals allow type I phase matching for laser wavelengths >= 1.0103 µm. In addition, a new monoclinic (s.g. C2) antimony(III) tartrate of composition Mg[Sb3((+)C4H2O6)2((+)C4H4O6)((+)C4H5O6)].11H2O and its crystal structure, which contains a novel type of antimony tartrate complex group [Sb3(C4H2O6)2(C4H4O6)(C4H5O6)], is presented.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/EF15_003%2F0000417" target="_blank" >EF15_003/0000417: Center for Advanced Materials: Design, Synthesis, and Applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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