Effect of the gravitational field strength on the rate of chemical reactions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F24%3A10482797" target="_blank" >RIV/00216208:11310/24:10482797 - isvavai.cz</a>

Result on the web

<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=Sl2kVi5_eV" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=Sl2kVi5_eV</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1515/phys-2024-0062" target="_blank" >10.1515/phys-2024-0062</a>

Result language

angličtina

Original language name

Effect of the gravitational field strength on the rate of chemical reactions

Original language description

The magnitude of the rate of chemical reactions also depends on the position in the gravitational field where a chemical reaction is being carried out. The rate of chemical reaction conducted at a stronger gravitational field, i.e., near the surface of some heavy planet, is slower than the rate of reaction conducted at a weaker gravitational field, i.e., away from the surface of a heavy plant, provided temperature and pressure are kept constant at two positions in the gravitational field. The effect of gravity on the rates of reactions has been shown by formulating the rate constants from almost all types of reaction rate theories, i.e., transition state theory, collision theory, Rice-Ramsperger-Kassel-Marcus, and Marcus&apos;s theory, in the language of the general theory of relativity. The gravitational transformation of the Boltzmann constant and the energy quantum levels of molecules have been developed quantum mechanically. A gravitational transformation of thermodynamic state functions has been formulated that successfully explains the quasi-equilibrium existing between reactants and the activated complex at different gravitational fields. Gravitational mass dilation has been developed, which explains that at weaker gravitational fields, the transition states possess more kinetic energy to sweep translation on the reaction coordinate, resulting in the faster conversion of reactants into products. The gravitational transformation of the half-life equation shows gravitational time dilation for the half-life period of chemical reactions and thus renders the general theory of relativity and the present theory in accord with each other.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10403 - Physical chemistry

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2024

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Open Physics

ISSN

2391-5471

e-ISSN

2391-5471

Volume of the periodical

22

Issue of the periodical within the volume

1

Country of publishing house

PL - POLAND

Number of pages

15

Pages from-to

20240062

UT code for WoS article

001277816700001

EID of the result in the Scopus database

2-s2.0-85199919332