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Shedding electrons on ADOR zeolite structures – Structure determination by 3DED

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F25%3A10497894" target="_blank" >RIV/00216208:11310/25:10497894 - isvavai.cz</a>

  • Result on the web

    <a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=SjVdvUPH0q" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=SjVdvUPH0q</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.micromeso.2025.113514" target="_blank" >10.1016/j.micromeso.2025.113514</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Shedding electrons on ADOR zeolite structures – Structure determination by 3DED

  • Original language description

    Three-dimensional electron diffraction (3DED) offers a powerful alternative to single-crystal X-ray diffraction (SCXRD) for the structure determination of crystalline materials with small-sized crystals (usually nanometresized) or crystals with intergrowths, often produced during zeolite synthesis. ADOR is a synthesis strategy of novel daughter zeolites from well-known parent germanosilicates. Structure determination of such ADOR zeolites is challenging due to the presence of aggregated intergrowths, and often small-sized crystals. This work demonstrates the application of continuous rotation electron diffraction (cRED), a type of 3DED, for the rapid structural characterisation of zeolites produced by ADOR approach. cRED can be performed in a transmission electron microscope and the structure of a studied material can be obtained rapidly. We propose a unified workflow for the structure determination of ADOR daughter materials. This workflow involves the initial structural investigation and determination of the parent material, followed by the utilization of this knowledge to facilitate the subsequent structure determination of the daughter material. Investigation strategy was shown to be uniform, as presented for ADOR transformation of two different parent germanosilicates. This approach is a tool allowing prompt recognition of new ADOR zeolites at the early stage of their synthesis and can be used for a feedback-based optimisation of synthesis conditions.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Microporous and Mesoporous Materials

  • ISSN

    1387-1811

  • e-ISSN

    1873-3093

  • Volume of the periodical

    387

  • Issue of the periodical within the volume

    April

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    10

  • Pages from-to

    113514

  • UT code for WoS article

    001412693600001

  • EID of the result in the Scopus database

    2-s2.0-85216094955