Progress and expansion of ADOR zeolites
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F25%3A10499885" target="_blank" >RIV/00216208:11310/25:10499885 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=hwSbjloBni" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=hwSbjloBni</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.micromeso.2025.113738" target="_blank" >10.1016/j.micromeso.2025.113738</a>
Alternative languages
Result language
angličtina
Original language name
Progress and expansion of ADOR zeolites
Original language description
Selective disassembly of zeolites to provide building blocks for controllable reassembly into new 3-dimensional and expanded structures has been hindered by the overall robustness of their frameworks. Zeolite UTL with high content of germanium atoms located predominantly in its D4R units proved to be susceptible to hydrolysis producing 1 nm thick layers that could be reorganized and reassembled yielding new zeolites including unfeasible ones based on thermodynamics of conventional bottom-up zeolite syntheses. This Assembly (of UTL)-Disassembly (into layers)-Organization-Reassembly (new structures), abbreviated ADOR, has been extended to other frameworks making it a general strategy for similar high-Ge zeolites and possibly others with built-in weakness enabling disassembly into 2D and potentially 1D periodic units. UTL has provided the largest number of diverse structures, both 3D frameworks and 2D architectures, so it is discussed in this perspective as the model system and template for developing analogous materials with other zeolites. Its notable features include continuously tunable porosity through hydrolysis dependent on acid concentration and organization into 4 different structures by layer shifts. These processes are controlled by Ge concentration and distribution, crystal properties and other variables, which must be worked out for other zeolites. The perspective includes possibilities for future developments and issues to be investigated.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Microporous and Mesoporous Materials
ISSN
1387-1811
e-ISSN
1873-3093
Volume of the periodical
397
Issue of the periodical within the volume
November
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
113738
UT code for WoS article
001529728800001
EID of the result in the Scopus database
2-s2.0-105035698340