Large Hydrogen Capacity in Hydrides R2Ni2In-H (R = La, Ce, Pr, Nd) With New Structure Type

Result code in IS VaVaI

RIV/00216208:11320/09:00206684 - isvavai.cz

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Large Hydrogen Capacity in Hydrides R2Ni2In-H (R = La, Ce, Pr, Nd) With New Structure Type

Original language description

Several new hydrides from the series R2Ni2InHx (R = La, Ce, Pr, Nd; x 4.5 - 5.0) were synthesized. They are based on initial compounds of the R2Ni2In type crystallizing in the Mo2FeB2-structure. So as to accommodate high amount of H atoms (x can theoretically reach the value of 6), the structure changes to orthorhombic, space group Pbam, while the unit-cell volume increases by 10-20 %. Nd2Ni2In was found antiferromagnetic, with a first order magnetic phase transition at TN = 8 K. Applied magnetic fieldmoH { 0.3 T induces ferromagnetism. TN of Nd2Ni2InH4.5, which is a more regular antiferromagnet, is reduced to 5 K.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

GA202/07/0418: Complex hydrides of f-metals: synthesis, structure and electronic properties

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Alloys and Compounds

ISSN

0925-8388

e-ISSN

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Volume of the periodical

477

Issue of the periodical within the volume

1-2

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

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UT code for WoS article

000266386400044

EID of the result in the Scopus database

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