The oxidative polymerization of p-phenylenediamine with silver nitrate: Towards highly conducting micro/nanostructured silver/conjugated polymer composites,
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F11%3A10104625" target="_blank" >RIV/00216208:11320/11:10104625 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/pola.24775" target="_blank" >http://dx.doi.org/10.1002/pola.24775</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/pola.24775" target="_blank" >10.1002/pola.24775</a>
Alternative languages
Result language
angličtina
Original language name
The oxidative polymerization of p-phenylenediamine with silver nitrate: Towards highly conducting micro/nanostructured silver/conjugated polymer composites,
Original language description
The oxidative polymerization of p-phenylenediamine with silver nitrate by using various oxidant/monomer mole ratios in aqueous solutions of both acetic and nitric acid was studied experimentally and computationally. The produced micro/nanostructured conducting poly(p-phenylenediamine)- silver composites, reaching the conductivities }104 S/cm, were characterized by conductivity and density measurements, gel permeation chromatography, transmission electron microscopy, UV-visible, FTIR, and Raman spectroscopies. The highest conductivity was 31,700 S/cm for poly(p-phenylenediamine) base-silver (81.4 wt % Ag). The unexpected increase of conductivity after deprotonation of polymer component is discussed on the basis of interfacial electrical barriers and their removal. Theoretical study of the mechanism of p-phenylenediamine oxidation has been based on the AM1 semi-empirical quantum chemical computations of the heat of formation of the reaction intermediates, taking into account the influenc
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
<a href="/en/project/IAA400500905" target="_blank" >IAA400500905: Preparation and properties of nanostructures produced by condcuting polymers</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Polymer Science, Part A: Polymer Chemistry
ISSN
0887-624X
e-ISSN
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Volume of the periodical
49
Issue of the periodical within the volume
15
Country of publishing house
US - UNITED STATES
Number of pages
17
Pages from-to
3387-3403
UT code for WoS article
000293279500016
EID of the result in the Scopus database
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