TiO2 powders synthesized by pressurized fluid extraction and supercritical drying: Effect of water and methanol on structural properties and purity

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F12%3A10126687" target="_blank" >RIV/00216208:11320/12:10126687 - isvavai.cz</a>
Alternative codes found
RIV/61388971:_____/12:00380909 RIV/67985858:_____/12:00380909
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0025540812005016" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0025540812005016</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.materresbull.2012.06.062" target="_blank" >10.1016/j.materresbull.2012.06.062</a>

Result language
angličtina
Original language name
TiO2 powders synthesized by pressurized fluid extraction and supercritical drying: Effect of water and methanol on structural properties and purity
Original language description
Pressurized water extraction followed by sub/supercritical methanol drying was used for synthesis of TiO2 from gels prepared by sol-gel technique using Triton X-114 like template. It was proved that pressurized water causes titania crystallization. Subsequent sub/supercritical methanol drying is responsible for total elimination of the rest of organic phase originating from the template. The impact of temperature and pressure modifications on titania purity was more essential for pressurized water extraction. The specific surface area significantly increases with removal of the residual organic phase. Anatase was a dominant crystalline phase. The fraction of minor brookite was in the range 20-30 wt.%. In situ XRD showed stability of titania crystallites size up to 300 degrees C and the presence of brookite crystallites even up to 600 degrees C. The correlation between Raman FWHM and XRD crystallite size was not influenced by the presence of organic phase and was more sensitive for anat
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
<a href="/en/project/GP104%2F09%2FP290" target="_blank" >GP104/09/P290: Innovative preparation of nanocrystalline metal oxides with high-ordered mesoporous structure by extraction techniques</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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