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Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F14%3A10271606" target="_blank" >RIV/00216208:11320/14:10271606 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/chem.201304423" target="_blank" >http://dx.doi.org/10.1002/chem.201304423</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/chem.201304423" target="_blank" >10.1002/chem.201304423</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules

  • Original language description

    The transformation of Mn-II glycolates (glc) between the three-dimensional coordination polymer [Mn(glc)(2)](n) (1) and discrete mononuclear phase [Mn(glc)(2)(H2O)(2)] (2) can be reversibly switched by water molecules, which dramatically change the magnetocaloric effect (MCE) of Mn-II glycolates from the maximum of 6.9Jkg(-1)K(-1) in 1 to 60.3Jkg(-1)K(-1) in 2. This case example reveals that the effect of magnetic coupling on MCE plays a dominant role over that of other factors such as magnetic densityfor 3d-type magnetic refrigerants.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LM2011025" target="_blank" >LM2011025: MLTL - Magnetism and Low Temperature Laboratories - operation and development of national research infrastructure</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemistry - A European Journal

  • ISSN

    0947-6539

  • e-ISSN

  • Volume of the periodical

    20

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    3029-3035

  • UT code for WoS article

    000332043500010

  • EID of the result in the Scopus database