The Mechanism of Hydrocarbon Oxygenate Reforming: C-C Bond Scission, Carbon Formation, and Noble-Metal-Free Oxide Catalysts
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F14%3A10288985" target="_blank" >RIV/00216208:11320/14:10288985 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/cssc.201301000" target="_blank" >http://dx.doi.org/10.1002/cssc.201301000</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cssc.201301000" target="_blank" >10.1002/cssc.201301000</a>
Alternative languages
Result language
angličtina
Original language name
The Mechanism of Hydrocarbon Oxygenate Reforming: C-C Bond Scission, Carbon Formation, and Noble-Metal-Free Oxide Catalysts
Original language description
Towards a molecular understanding of the mechanism behind catalytic reforming of bioderived hydrocarbon oxygenates, we explore the C-C bond scission of C-2 model compounds (acetic acid, ethanol, ethylene glycol) on ceria model catalysts of different complexity, with and without platinum. Synchrotron photoelectron spectroscopy reveals that the reaction pathway depends very specifically on both the reactant molecule and the catalyst surface. Whereas C-C bond scission on Pt sites and on oxygen vacancies involves intermittent surface carbon species, the reaction occurs without any carbon formation and deposition for ethylene glycol on CeO2(111).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemSusChem
ISSN
1864-5631
e-ISSN
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Volume of the periodical
7
Issue of the periodical within the volume
1
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
77-81
UT code for WoS article
000336802400006
EID of the result in the Scopus database
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