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Defects and sintering-induced diffusion processes in yttria-stabilised zirconia nanomaterials studied by positron annihilation spectroscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F14%3A10290420" target="_blank" >RIV/00216208:11320/14:10290420 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.scientific.net/DF.1.155" target="_blank" >http://www.scientific.net/DF.1.155</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.4028/www.scientific.net/DF.1.155" target="_blank" >10.4028/www.scientific.net/DF.1.155</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Defects and sintering-induced diffusion processes in yttria-stabilised zirconia nanomaterials studied by positron annihilation spectroscopy

  • Original language description

    In the present work, zirconia (ZrO2) nanopowders doped with yttria (Y2O3) and chromia (Cr2O3) were prepared by a co-precipitation technique. The nanopowders were then subjected to a calcination and a successive sintering at elevated temperatures up to 1500 C. The nanostructures in these nanomaterials were characterized by positron annihilation spectroscopy (positron lifetimes and Doppler broadening measurements) which is a non-destructive technique with a high sensitivity to atomic-scale open-volume defects. It was found that the zirconia-based nanomaterials studied contain vacancy-like defects and nano-scale pores. Diffusion processes induced in these nanomaterials by sintering were investigated also by depth sensitive positron annihilation studies using a variable energy slow positron beam. Sintering was found to cause intensive grain growth and a removal of porosity by a migration of pores from the sample interior toward its surface.

  • Czech name

  • Czech description

Classification

  • Type

    C - Chapter in a specialist book

  • CEP classification

    JH - Ceramics, fire-proof materials and glass

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP108%2F11%2F1396" target="_blank" >GAP108/11/1396: Effect of substitutional elements and grain boundaries on properties of nanocrystalline zirconia-based materials</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Book/collection name

    Diffusion in Advanced Materials

  • ISBN

    978-3-03835-081-1

  • Number of pages of the result

    19

  • Pages from-to

    155-172

  • Number of pages of the book

    218

  • Publisher name

    TRANS TECH PUBLICATIONS LTD

  • Place of publication

    Switzerland

  • UT code for WoS chapter