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In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO2 Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F15%3A10319417" target="_blank" >RIV/00216208:11320/15:10319417 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/anie.201410697" target="_blank" >http://dx.doi.org/10.1002/anie.201410697</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/anie.201410697" target="_blank" >10.1002/anie.201410697</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO2 Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds

  • Original language description

    Water dissociation is crucial in many catalytic reactions on oxide-supported transition-metal catalysts. Supported by experimental and density-functional theory results, the effect of the support on O-H bond cleavage activity is elucidated for nickel/ceria systems. Ambient-pressure O1s photoemission spectra at low Ni loadings on CeO2(111) reveal a substantially larger amount of OH groups as compared to the bare support. Computed activation energy barriers for water dissociation show an enhanced reactivity of Ni adatoms on CeO2(111) compared with pyramidal Ni-4 particles with one Ni atom not in contact with the support, and extended Ni(111) surfaces. At the origin of this support effect is the ability of ceria to stabilize oxidized Ni2+ species by accommodating electrons in localized f-states. The fast dissociation of water on Ni/CeO2 has a dramatic effect on the activity and stability of this system as a catalyst for the water-gas shift and ethanol steam reforming reactions.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LH11017" target="_blank" >LH11017: Investigation of Catalytic Processes using Inverse Model Catalysts</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Angewandte Chemie - International Edition

  • ISSN

    1433-7851

  • e-ISSN

  • Volume of the periodical

    54

  • Issue of the periodical within the volume

    13

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    3917-3921

  • UT code for WoS article

    000351204600009

  • EID of the result in the Scopus database

    2-s2.0-84924917072