Photoemission Study of Methanol Adsorption and Decomposition on Pd/CeO2(111)/Cu(111) Thin Film Model Catalyst
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F15%3A10319543" target="_blank" >RIV/00216208:11320/15:10319543 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10562-015-1557-9" target="_blank" >http://dx.doi.org/10.1007/s10562-015-1557-9</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10562-015-1557-9" target="_blank" >10.1007/s10562-015-1557-9</a>
Alternative languages
Result language
angličtina
Original language name
Photoemission Study of Methanol Adsorption and Decomposition on Pd/CeO2(111)/Cu(111) Thin Film Model Catalyst
Original language description
This photoelectron spectroscopy (PES) study compares the adsorption and subsequent decomposition of methanol on a Pd(111) single crystal and Pd particles on a CeO2(111)/Cu(111) thin film surface investigated by means of XPS and soft X-ray synchrotron-radiation-excited PES. Resonance PES (Ce 4d -> 4f transitions) was used to determine the Pd deposit and cerium oxide surface interaction with high sensitivity. Methanol adsorbed at low temperature formed adsorbate multilayers, which were consecutively desorbed upon stepwise annealing to 600 K. The results obtained on Pd/CeO2(111) showed a more complex decomposition process involving different possible pathways compared to the single pathway decomposition to CO on the Pd(111) surface. [GRAPHICS] .
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Catalysis Letters
ISSN
1011-372X
e-ISSN
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Volume of the periodical
145
Issue of the periodical within the volume
7
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
1474-1482
UT code for WoS article
000357481900014
EID of the result in the Scopus database
2-s2.0-84945473926