The Role of Resonant Vibrations in Electronic Energy Transfer
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F16%3A10333727" target="_blank" >RIV/00216208:11320/16:10333727 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/cphc.201500965" target="_blank" >http://dx.doi.org/10.1002/cphc.201500965</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cphc.201500965" target="_blank" >10.1002/cphc.201500965</a>
Alternative languages
Result language
angličtina
Original language name
The Role of Resonant Vibrations in Electronic Energy Transfer
Original language description
Nuclear vibrations play a prominent role in the spectroscopy and dynamics of electronic systems. As recent experimental and theoretical studies suggest, this may be even more so when vibrational frequencies are resonant with transitions between the electronic states. Herein, a vibronic multilevel Redfield model is reported for excitonically coupled electronic two-level systems with a few explicitly included vibrational modes and interacting with a phonon bath. With numerical simulations the effects of the quantized vibrations on the dynamics of energy transfer and coherence in a model dimer are illustrated. The resonance between the vibrational frequency and energy gap between the sites leads to a large delocalization of vibronic states, which then results in faster energy transfer and longer-lived mixed coherences.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-25752S" target="_blank" >GA14-25752S: Microscopic environmental determinants and self-regulation of photosynthetic energy transfer</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN
1439-4235
e-ISSN
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Volume of the periodical
17
Issue of the periodical within the volume
9
Country of publishing house
DE - GERMANY
Number of pages
13
Pages from-to
1356-1368
UT code for WoS article
000376003400015
EID of the result in the Scopus database
2-s2.0-84961793415