Binary and ternary recombination of H2D+ and HD2+ ions with electrons at 80 K
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F16%3A10334278" target="_blank" >RIV/00216208:11320/16:10334278 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c6cp04152c" target="_blank" >http://dx.doi.org/10.1039/c6cp04152c</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c6cp04152c" target="_blank" >10.1039/c6cp04152c</a>
Alternative languages
Result language
angličtina
Original language name
Binary and ternary recombination of H2D+ and HD2+ ions with electrons at 80 K
Original language description
The recombination of deuterated trihydrogen cations with electrons has been studied in afterglow plasmas containing mixtures of helium, argon, hydrogen and deuterium. By monitoring the fractional abundances of H-3(+), H2D+, HD2+ and D-3(+) as a function of the [D-2]/[H-2] ratio using infrared absorption observed in a cavity ring down absorption spectrometer (CRDS), it was possible to deduce effective recombination rate coefficients for H2D+ and HD2+ ions at a temperature of 80 K. From pressure dependences of the measured effective recombination rate coefficients the binary and the ternary recombination rate coefficients for both ions have been determined. The inferred binary and ternary recombination rate coefficients are: alpha(binH2D)(80 K) = (7.1 +/- 4.2) x 10(-8) cm(3) s(-1), alpha(binHD2) (80 K) = (8.7 +/- 2.5) x 10(-8) cm(3) s(-1), K-H2D(80 K) = (1.1 +/- 0.6) x 10(-25) cm(6) s(-1) and K-HD2 (80 K) = (1.5 +/- 0.4) x 10(-25) cm(6) s(-1).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BL - Plasma physics and discharge through gases
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Chemistry Chemical Physics
ISSN
1463-9076
e-ISSN
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Volume of the periodical
18
Issue of the periodical within the volume
34
Country of publishing house
GB - UNITED KINGDOM
Number of pages
5
Pages from-to
23549-23553
UT code for WoS article
000382107200013
EID of the result in the Scopus database
2-s2.0-84984985040