Adsorption of ethylene on Sn and In terminated Si(001) surface studied by photoelectron spectroscopy and scanning tunneling microscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F16%3A10334294" target="_blank" >RIV/00216208:11320/16:10334294 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1063/1.4961737" target="_blank" >http://dx.doi.org/10.1063/1.4961737</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1063/1.4961737" target="_blank" >10.1063/1.4961737</a>
Alternative languages
Result language
angličtina
Original language name
Adsorption of ethylene on Sn and In terminated Si(001) surface studied by photoelectron spectroscopy and scanning tunneling microscopy
Original language description
Interaction of ethylene (C2H4) with Si(001)-Sn-2 x 2 and Si(001)-In-2 x 2 at room temperature has been studied using core level (C 1s) X-ray photoelectron spectroscopy with synchrotron radiation and scanning tunneling microscopy. Sn and In form similar dimer chains on Si(001) 2 x 1, but exhibit different interaction with ethylene. While ethylene adsorbs on top of Sn dimers of the Si(001)-Sn-2 x 2 surface, the Si(001)-In-2 x 2 surface turned out to be inert. Furthermore, the reactivity of the Sn terminated surface is found to be considerably decreased in comparison with Si(001) 2 x 1. According to the proposed adsorption model ethylene bonds to Sn dimers via [2 + 2] cycloaddition by interacting with their pi dimer bonds. In contrast, indium dimers do not contain p bonds, which renders the In terminated Si(001) surface inert for ethylene adsorption. Published by AIP Publishing.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Physics
ISSN
0021-9606
e-ISSN
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Volume of the periodical
145
Issue of the periodical within the volume
9
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
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UT code for WoS article
000383957800024
EID of the result in the Scopus database
2-s2.0-84985982510