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Adsorption of ethylene on Sn and In terminated Si(001) surface studied by photoelectron spectroscopy and scanning tunneling microscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F16%3A10334294" target="_blank" >RIV/00216208:11320/16:10334294 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1063/1.4961737" target="_blank" >http://dx.doi.org/10.1063/1.4961737</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1063/1.4961737" target="_blank" >10.1063/1.4961737</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Adsorption of ethylene on Sn and In terminated Si(001) surface studied by photoelectron spectroscopy and scanning tunneling microscopy

  • Original language description

    Interaction of ethylene (C2H4) with Si(001)-Sn-2 x 2 and Si(001)-In-2 x 2 at room temperature has been studied using core level (C 1s) X-ray photoelectron spectroscopy with synchrotron radiation and scanning tunneling microscopy. Sn and In form similar dimer chains on Si(001) 2 x 1, but exhibit different interaction with ethylene. While ethylene adsorbs on top of Sn dimers of the Si(001)-Sn-2 x 2 surface, the Si(001)-In-2 x 2 surface turned out to be inert. Furthermore, the reactivity of the Sn terminated surface is found to be considerably decreased in comparison with Si(001) 2 x 1. According to the proposed adsorption model ethylene bonds to Sn dimers via [2 + 2] cycloaddition by interacting with their pi dimer bonds. In contrast, indium dimers do not contain p bonds, which renders the In terminated Si(001) surface inert for ethylene adsorption. Published by AIP Publishing.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chemical Physics

  • ISSN

    0021-9606

  • e-ISSN

  • Volume of the periodical

    145

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

  • UT code for WoS article

    000383957800024

  • EID of the result in the Scopus database

    2-s2.0-84985982510