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Structural, magnetic and magnetocaloric properties of NdPrFe14B and its hydrides

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F19%3A10419193" target="_blank" >RIV/00216208:11320/19:10419193 - isvavai.cz</a>

  • Alternative codes found

    RIV/68378271:_____/19:00520916

  • Result on the web

    <a href="https://doi.org/10.1088/1742-6596/1389/1/012094" target="_blank" >https://doi.org/10.1088/1742-6596/1389/1/012094</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1088/1742-6596/1389/1/012094" target="_blank" >10.1088/1742-6596/1389/1/012094</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structural, magnetic and magnetocaloric properties of NdPrFe14B and its hydrides

  • Original language description

    A systematic study of the influence of interstitial hydrogen on the structure, morphology of surface, magnetic and magnetothermal properties in multicomponent (Nd0.5Pr0.5)(2)Fe14BHx (x = 0; 2.7; 4.3) are reported. Partial substitution of Pr for Nd allows a decrease of the spin-reorientation transition temperature from 135 K for Nd2Fe14B to 73 K for (Nd0.5Pr0.5)(2)Fe14B. Hydrides (Nd0.5Pr0.5)(2)Fe14BHx crystallize in a tetragonal crystal structure (space group P42/mnm) of the Nd2Fe14B-type. Both lattice constants and unit cell volume increase upon hydrogen absorption. It was also found that the surface of the hydrogenated sample was very severely damaged by the introduction of hydrogen. Magnetic studies of both initial compound and the hydrides were performed on bulk and powder samples in static and pulsed magnetic fields up to 14 and 58 T, respectively. Hydrogenation has a significant effect on magnetic properties of a multicomponent alloy (Nd0.5Pr0.5)(2)Fe14B: Curie temperature and saturation magnetization increase, while temperature of SRT decreases (T-SRT = 63 K for (Nd0.5Pr0.5)(2)Fe14BHx with x = 2.7 and 4.3). The magnetocaloric effect (MCE) in the range of spin-reorientation transition also decreases significantly. We analyzed magnetic properties of (Nd0.5Pr0.5)(2)Fe14BHx and compare them with that of Nd2Fe14BHx . Magnetic phase diagrams are constructed.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    <a href="/en/project/LM2018096" target="_blank" >LM2018096: Materials Growth and Measurement Laboratory</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Journal of Physics: Conference Series

  • ISBN

  • ISSN

    1742-6588

  • e-ISSN

    1742-6596

  • Number of pages

    7

  • Pages from-to

  • Publisher name

    IOP PUBLISHING LTD

  • Place of publication

    BRISTOL

  • Event location

    RAS

  • Event date

    Sep 8, 2019

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article

    000562319800094