Ferrocene self assembled monolayer as a redox mediator for triggering ion transfer across nanometer-sized membranes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F19%3A10425350" target="_blank" >RIV/00216208:11320/19:10425350 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=S.Iaf3hunV" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=S.Iaf3hunV</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2019.05.091" target="_blank" >10.1016/j.electacta.2019.05.091</a>
Alternative languages
Result language
angličtina
Original language name
Ferrocene self assembled monolayer as a redox mediator for triggering ion transfer across nanometer-sized membranes
Original language description
Modulation of ion-transfer processes across nanometer-sized voltammetry membranes by ferrocene-based self-assembled monolayer on regular glassy carbon electrode is herein demonstrated. The composition of the membrane is advantageously tuned to promote either cation or anion transfer: the presence of an exchangeable cation results in cation transfer, whereas a lipophilic salt induces anion transfer through the fulfilment of the electroneutrality of the system. When an anodic scan oxidizes ferrocene moieties in the monolayer, these are stabilized by the pairing of lipophilic anions present in the membrane. As a result, either, hydrophilic cations present in the membrane are expelled into the solution or anions enter from the solution generating hence reversible and voltammetric waves for these transfers. The use of a redox active monolayer rather than a conducting polymer film or a redox active compound into the membrane overcomes a number of drawbacks previously manifested by these systems. The confinement of the redox process in a thin film at the immediate vicinity of the membrane allows to avoid the need of elevated number of redox moieties to be sued in the membrane, therefore suppressing its acute leaching and being compatible with the incorporation of both cation and anion ionophores for the first time. In this sense, assisted transfer of lithium and chloride are shown as proof-of-concept. Here, the peak potential of the associated voltammetric waves shifts according to the Nernst equation, in analogy to potentiometric sensors. Analytical detection of lithium and chloride ions in real samples is additionally presented. (C) 2019 The Authors. Published by Elsevier Ltd.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10305 - Fluids and plasma physics (including surface physics)
Result continuities
Project
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Continuities
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Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochimica Acta
ISSN
0013-4686
e-ISSN
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Volume of the periodical
315
Issue of the periodical within the volume
Aug
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
84-93
UT code for WoS article
000470108800011
EID of the result in the Scopus database
2-s2.0-85066091769