Open-Circuit Voltage Comes from Non-Equilibrium Thermodynamics
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F21%3A10422096" target="_blank" >RIV/00216208:11320/21:10422096 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/21:43922912
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=VKxVXjVTWr" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=VKxVXjVTWr</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/jnet-2020-0070" target="_blank" >10.1515/jnet-2020-0070</a>
Alternative languages
Result language
angličtina
Original language name
Open-Circuit Voltage Comes from Non-Equilibrium Thermodynamics
Original language description
Originally derived by Walther Nernst more than a century ago, the Nernst equation for the opencircuit voltage is a cornerstone in the analysis of electrochemical systems. Unfortunately, the assumptions behind its derivation are often overlooked in the literature, leading to incorrect forms of the equation when applied to complex systems (for example, those with ion-exchange membranes or involving mixed potentials). Such flaws can be avoided by applying a correct thermodynamic derivation independently of the form in which the electrochemical reactions are written. The proper derivation of the Nernst equation becomes important, for instance, in modeling of vanadium redox flow batteries or zinc-air batteries. The rigorous path towards the Nernst equation derivation starts in non-equilibrium thermodynamics.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10102 - Applied mathematics
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Non-Equilibrium Thermodynamics
ISSN
0340-0204
e-ISSN
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Volume of the periodical
46
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
18
Pages from-to
91-108
UT code for WoS article
000605606300007
EID of the result in the Scopus database
2-s2.0-85095564970