All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Separating single- from multi-particle dynamics in nonlinear spectroscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11320%2F23%3A10476119" target="_blank" >RIV/00216208:11320/23:10476119 - isvavai.cz</a>

  • Result on the web

    <a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=gyBy98zTGG" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=gyBy98zTGG</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1038/s41586-023-05846-7" target="_blank" >10.1038/s41586-023-05846-7</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Separating single- from multi-particle dynamics in nonlinear spectroscopy

  • Original language description

    Quantum states depend on the coordinates of all their constituent particles, with essential multi-particle correlations. Time-resolved laser spectroscopy(1) is widely used to probe the energies and dynamics of excited particles and quasiparticles such as electrons and holes(2,3), excitons(4-6), plasmons(7), polaritons(8) or phonons(9). However, nonlinear signals from single- and multiple-particle excitations are all present simultaneously and cannot be disentangled without a priori knowledge of the system(4,10). Here, we show that transient absorption-the most commonly used nonlinear spectroscopy-with N prescribed excitation intensities allows separation of the dynamics into N increasingly nonlinear contributions; in systems well-described by discrete excitations, these N contributions systematically report on zero to N excitations. We obtain clean single-particle dynamics even at high excitation intensities and can systematically increase the number of interacting particles, infer their interaction energies and reconstruct their dynamics, which are not measurable via conventional means. We extract single- and multiple-exciton dynamics in squaraine polymers(11,12) and, contrary to common assumption(6,13), we find that the excitons, on average, meet several times before annihilating. This surprising ability of excitons to survive encounters is important for efficient organic photovoltaics(14,15). As we demonstrate on five diverse systems, our procedure is general, independent of the measured system or type of observed (quasi)particle and straightforward to implement. We envision future applicability in the probing of (quasi)particle interactions in such diverse areas as plasmonics(7), Auger recombination(2) and exciton correlations in quantum dots(5,16,17), singlet fission(18), exciton interactions in two-dimensional materials(19) and in molecules(20,21), carrier multiplication(22), multiphonon scattering(9) or polariton-polariton interaction(8).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10301 - Atomic, molecular and chemical physics (physics of atoms and molecules including collision, interaction with radiation, magnetic resonances, Mössbauer effect)

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Nature

  • ISSN

    0028-0836

  • e-ISSN

    1476-4687

  • Volume of the periodical

    616

  • Issue of the periodical within the volume

    7956

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    13

  • Pages from-to

    280-292

  • UT code for WoS article

    000960436400001

  • EID of the result in the Scopus database

    2-s2.0-85150909628