The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F01%3A00004261" target="_blank" >RIV/00216224:14310/01:00004261 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

The synthesis and characterisation of bis(diisopropylphosphoryl)ferrocene Fe[(C5H4)P(O)i-Pr2]2, bis(diisopropylthiophosphoryl)ferrocene Fe[(C5H4)P(S)i-Pr2]2 and bis(diisopropylselenophosphoryl)ferrocene Fe[(C5H4)P(Se)i-Pr2]2

Original language description

The synthesis and spectroscopic characterisation of three chalcogenophosphoryl ligands derived from ferrocene is reported. The synthesis was based on the oxidation of Fe[(eta (5)-C5H4)P ' Pr-2](2) by elementary sulfur and selenium, and hydrogen peroxide,respectively. All new compounds were characterised by X-ray crystallography and comparison with their aryl analogues was made. Contrary to Fe[(eta(5)-C5H4)P(E)Ph-2](2) (E = O, S, Se), the prepared compounds are not centrosymmetric, with the iso-propyl groups showing more flexibility than the phenyl substituents.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F99%2F0067" target="_blank" >GA203/99/0067: Lease of crystallographic databases</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

20

Issue of the periodical within the volume

7-8

Country of publishing house

GB - UNITED KINGDOM

Number of pages

6

Pages from-to

741

UT code for WoS article

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EID of the result in the Scopus database

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