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Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F01%3A00004360" target="_blank" >RIV/00216224:14310/01:00004360 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves

  • Original language description

    In our experiments we concentrated on application of azomethine ylides stabilized by carbonyl in intramolecular cycloaddition reaction under microwave irradiation. Thus, aromatic aldehydes with gama-double bond in ortho-position bound chain afforded in the presence of secondary amine fused heterocyclic compounds.We tried to compare some of the known reactions carried at classical heating with newly substituted substrates in order to follow influence of substitution upon the reaction. Application of microwaves represents a new field of reaction conditions improvement as well as a way of compounds preparation in higher yield and shorter time comparatively with classical conditions and sometimes is very close to so called "green chemistry" when working without solvents.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2001

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings - 18th International Congres of Heterocyclic Chemistry

  • ISBN

  • ISSN

  • e-ISSN

  • Number of pages

    1

  • Pages from-to

    478

  • Publisher name

    Graduate School of Pharmaceutical Sciences, University of Tokyo

  • Place of publication

    Yokohama

  • Event location

    Yokohama

  • Event date

    Jan 1, 2001

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article