Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F01%3A00004360" target="_blank" >RIV/00216224:14310/01:00004360 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves
Original language description
In our experiments we concentrated on application of azomethine ylides stabilized by carbonyl in intramolecular cycloaddition reaction under microwave irradiation. Thus, aromatic aldehydes with gama-double bond in ortho-position bound chain afforded in the presence of secondary amine fused heterocyclic compounds.We tried to compare some of the known reactions carried at classical heating with newly substituted substrates in order to follow influence of substitution upon the reaction. Application of microwaves represents a new field of reaction conditions improvement as well as a way of compounds preparation in higher yield and shorter time comparatively with classical conditions and sometimes is very close to so called "green chemistry" when working without solvents.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings - 18th International Congres of Heterocyclic Chemistry
ISBN
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ISSN
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e-ISSN
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Number of pages
1
Pages from-to
478
Publisher name
Graduate School of Pharmaceutical Sciences, University of Tokyo
Place of publication
Yokohama
Event location
Yokohama
Event date
Jan 1, 2001
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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