Electrooxidation of small organic molecules on polycrystalline platinum electrode in aqueous acid solution using on-line MS study
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F01%3A00005177" target="_blank" >RIV/00216224:14310/01:00005177 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Electrooxidation of small organic molecules on polycrystalline platinum electrode in aqueous acid solution using on-line MS study
Original language description
The electrochemical cell and mass spectrometer combination - differential electrochemical mass spectrometry (DEMS) - was used for detection, identification and observation in time of volatile and semivolatile species during the electrochemical polarisation of a working electrode. DEMS is a type of experimental technique, which makes possible an investigation of electro-sorption, electro-oxidation and electro-hydrogenation processes of molecules like aromatic hydrocarbons, some other small organic molecules and reaction intermediates. As a test system the electrochemical oxidation of formic acid and dimethylformamide in 0,5 M sulfuric acid on polycrystalline Pt electrode was studied. The results are presented as a plot of ion current of selected massesof expected products as function of working electrode potential. The faradaic current-potential curves were measured simultaneously.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ME%20360" target="_blank" >ME 360: Differential Mass Spectrometry (DEMS) of Aromatic Compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of the 19th Informal Meeting on Mass Spectrometry
ISBN
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ISSN
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e-ISSN
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Number of pages
2
Pages from-to
98
Publisher name
MS Group of the Chemical Research Center of the Hungarian Academy of Sciences,Hungary and MS Service of CNR, Italy
Place of publication
Nosyvaj
Event location
Nosyvaj
Event date
Jan 1, 2001
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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