The reactivity of N3-Aryl-N1-(2-phenylquinazolin-4-yl)thioureas
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F01%3A00005235" target="_blank" >RIV/00216224:14310/01:00005235 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The reactivity of N3-Aryl-N1-(2-phenylquinazolin-4-yl)thioureas
Original language description
The model compound N3-aryl-N1-(2-phenyl-3,4-dihydroquinazolin-4-yl)thiourea 1 was synthesized in a Domino reaction of N2-(2-cyanophenyl)-N1-thioxomethylidenebenzene-1-carboximidamide with anilines. This compound reacts with alkyl halides, phenacyl bromides, chloroacetic acid derivatives, amines, amines in the presence of H2O2, amines in the presence of CH2O (under Mannich reaction conditions) and acyl halides to give a variety of compounds. The structure of these products together with the reason for there formation proved by quantum computational studies will be reported in this contribution. Compounds were identified by FTIR, 1H NMR, 13C NMR, X-ray, mass spectroscopy and by the ab initio computational.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F01%2F1333" target="_blank" >GA203/01/1333: Chalcogen organic compounds - synthesis, transformation and structure elucidation</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Sborník príspevkov 53. zjazd Chemických spoločností
ISBN
80-89029-22-1
ISSN
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e-ISSN
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Number of pages
2
Pages from-to
279
Publisher name
FPV Univerzita Mateja Bela v Banskej Bystrici
Place of publication
Banká Bystrica
Event location
Banká Bystrica
Event date
Jan 1, 2001
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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