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The reactivity of N3-Aryl-N1-(2-phenylquinazolin-4-yl)thioureas

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F01%3A00005235" target="_blank" >RIV/00216224:14310/01:00005235 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The reactivity of N3-Aryl-N1-(2-phenylquinazolin-4-yl)thioureas

  • Original language description

    The model compound N3-aryl-N1-(2-phenyl-3,4-dihydroquinazolin-4-yl)thiourea 1 was synthesized in a Domino reaction of N2-(2-cyanophenyl)-N1-thioxomethylidenebenzene-1-carboximidamide with anilines. This compound reacts with alkyl halides, phenacyl bromides, chloroacetic acid derivatives, amines, amines in the presence of H2O2, amines in the presence of CH2O (under Mannich reaction conditions) and acyl halides to give a variety of compounds. The structure of these products together with the reason for there formation proved by quantum computational studies will be reported in this contribution. Compounds were identified by FTIR, 1H NMR, 13C NMR, X-ray, mass spectroscopy and by the ab initio computational.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F01%2F1333" target="_blank" >GA203/01/1333: Chalcogen organic compounds - synthesis, transformation and structure elucidation</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2001

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Sborník príspevkov 53. zjazd Chemických spoločností

  • ISBN

    80-89029-22-1

  • ISSN

  • e-ISSN

  • Number of pages

    2

  • Pages from-to

    279

  • Publisher name

    FPV Univerzita Mateja Bela v Banskej Bystrici

  • Place of publication

    Banká Bystrica

  • Event location

    Banká Bystrica

  • Event date

    Jan 1, 2001

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article