Coupling reactions on bicyclo[1.1.1]pentane cage bridgeheads

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F03%3A00009422" target="_blank" >RIV/00216224:14310/03:00009422 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Coupling reactions on bicyclo[1.1.1]pentane cage bridgeheads

Original language description

Experimental effort disclosing the possibility of transition-metal mediated cross-coupling reactions on electrophilic bicyclo[1.1.1]pentane cage bridgeheads is described. It has been shown that the bridgehead-halogen bond in bicyclo[1.1.1]pentanes can undergo oxidative addition towards low-valent nickel species, yielding a new complex which reacts with organomagnesium or organolithium reagents to form a new C-C bond. Thus, the unsymmetrically substituted bicyclo[1.1.1]pentane derivatives posessing, forexample, aryl funcional moieties on the bridgeheads could be prepared. Likewise, the protocol could be applied to the synthesis of [1.1.1]propellane oligomers ([n]staffanes), a class of compounds exploitable as the building blocks for supramolecular chemistry and molecular electronics

Czech name

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Czech description

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Type

D - Article in proceedings

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

YoungChem 2003, Book of Abstracts

ISBN

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ISSN

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e-ISSN

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Number of pages

1

Pages from-to

"T23"-"T23"

Publisher name

Chemical Scientific Set "Flogiston", Warsaw University of Technology

Place of publication

Warsaw

Event location

Zakopane, Polsko

Event date

Oct 22, 2003

Type of event by nationality

EUR - Evropská akce

UT code for WoS article

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