Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)]. 4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2=thiodiglycolic acid)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010077" target="_blank" >RIV/00216224:14310/04:00010077 - isvavai.cz</a>

Alternative codes found

RIV/61989592:15310/04:00002141 RIV/61989592:15310/04:00009894

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)]. 4H2O and [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2=thiodiglycolic acid)

Original language description

Mixed-ligand Ni(II) complexes involving thiodiglycolate(2-) anion (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H2O (1), [(en)Ni(-tdga)2Ni(en)].4H2O (2), [Ni(phen)(tdga)(H2O)] (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where BPY=2,2Ąä-bipyridine, EN=ethylenediamine, PHEN=1,10-phenanthroline, 1,8-dan=1,8-diaminonaphthalene, NPHEN=5-nitro-1,10-phenanthroline and AMPY=2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-Vis spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu eff/mu B. and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H2O (1). A binuclear structure of co

Czech name

Syntéza a charakterizace nikelnatých komplexů s kyselinou thiodiglykolovou a N-donorovými ligandy. Struktury [Ni(bpy)(tdga)(H2O)]. 4H2O a [(en)Ni(mu-tdga)2Ni(en)].4H2O (tdgaH2=thiodiglycolová kyselina)

Czech description

Byly připraveny různé směsné nikelnaté komplexy s N-donorovými ligandy a thiodiglykolovým aniontem. Výsledné sloučeniny byly charakterizovány fyzikálně chemickými metodami.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2004

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

23

Issue of the periodical within the volume

9

Country of publishing house

GB - UNITED KINGDOM

Number of pages

6

Pages from-to

1573-1578

UT code for WoS article

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EID of the result in the Scopus database

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