New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00021218" target="_blank" >RIV/00216224:14310/04:00021218 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group
Original language description
During our studies of the reactions of -N(H)SiMe3 and -N(Me)SiMe3 derivatives of Cl3PNSO2Cl with acetonitrile and BCl3 we have obtained six-membered polyheteroatomic cycles -P(Cl2)NSO2(Cl)N(H)C(Me)Nand -P(Cl2)NS(O)(Cl)OB(Cl2)N(Me) [1,2]. In the system Ph2PCl3, H2NSO2Cl and HN(SiMe3)2 we have identified and isolated several P-N-S cycles, e.g. the reaction of Ph2PCl3 with H2NSO2Cl gives Ph2ClPNSO2Cl [3] which with HN(SiMe3)2 reacts to ĄS(O2)N(H)P(Ph)2N(H)SO2N(H)P(Ph)2N(H), ĄS(O2)N(H)S(O2)N(H)P(Ph)2N(H)P(Ph)2N(H)and Ą[S(O2)N(H)P(Ph)2NP(Ph)2N(H)]+Cl-; Ph2PCl3 with HN(SiMe3)2 gives N[P(Ph)2N(H)SiMe3]2+ Cl-, and H2NSO2Cl with HN(SiMe3)2 leads to SO2(NHSiMe3)2. The reaction of Ph2PCl3 with HN(SiMe3)2 gives N(P(Ph)2NHSiMe3)2Cl in a very good yield which was further used to syntheses of metal-containing heterocycles. By the reaction of N[P(Ph)2N(H)SiMe3]2+Cl- with some covalent halogenides we have obtained six-membered heterocycles containing B, As, In, and Sn. The same cyclic compounds can als
Czech name
Nové polyheteroatomické molekuly obsahující prvky 13. - 16. skupiny
Czech description
Nové polyheteroatomické molekuly obsahující prvky 13. - 16. skupiny

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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