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Determination of cadmium by electrothermal atomic absorption spectrometry using electrochemical separation in a microcell

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F05%3A00014347" target="_blank" >RIV/00216224:14310/05:00014347 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Determination of cadmium by electrothermal atomic absorption spectrometry using electrochemical separation in a microcell

  • Original language description

    Electrodeposition on the graphite electrode under conditions of controlled current in a flow-through mode, followed by electrothermal atomic absorption spectrometry, is proposed for the determination of cadmium. After electrolysis in a microcell of 0.0026 ml volume, deposited metal was dissolved in 0.04 ml 0.2 M nitric acid and the whole volume was direct injected into the atomizer. The method was applied for the determination of cadmium in a real sample of seawater.

  • Czech name

    Stanovení kadmia atomovou absorpční spektrometrií s elektrotermickou atomizací po elektrochemické separaci v mikrocele

  • Czech description

    Elektrodepozice kovu na grafitové elektrodě v průtokovém uspořádání a ve spojení s atomovou absorpční spektrometrií s elektrotermickou atomizací je navržena pro stanovení kadmia. Po elektrolýze v mikrocele o objemu 0.0026 ml se kov rozpustí ve 0.04 ml 0,2 M kyseliny dusičné a celý objem je přímo dávkován do atomizátoru. Metoda byla aplikována na stanovení kadmia v mořské vodě.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2005

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Spectrochimica Acta Part B

  • ISSN

    0584-8547

  • e-ISSN

  • Volume of the periodical

    60

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

    393-398

  • UT code for WoS article

  • EID of the result in the Scopus database